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Once again, the Game Master's world of quests unexpectedly pulls in Yuusuke Yotsuya and the rest of this old team. Accompanied by the newest addition, Keita Torii, the team reunites with Kahabell, still unaware of their actions' impact on this world. After bidding Kahabell farewell, the team sets out on their newly appointed quest—an offering of a Jiffon Buffalo at Vaikdamnia on Jiffon Island. However, as their journey to the island commences, the team shortly finds that the quest is not as simple as it initially seemed. In fact, the island is terrorized by orcs that have made a deal with its inhabitants: instead of devouring the islanders, the orcs will be granted buffalo. With the growing shortage of buffalo, the annual Vaikdamnia festival cannot proceed. But, given the importance of the team's quest, they are left with the obvious choice—rid the island of the orcs and save the islanders. [Written by MAL Rewrite]

After inheriting the company from their parents, siblings Yuuhi and Yuamu Oudou have started to work at Ultraterrestrial Trouble Solutions, an organization that hunts aliens. Although they have never encountered aliens before, Yuuhi is desperate to meet one as he believes that an alien has stolen his important item called the "Earthdamar." One day, while searching for extraterrestrial creatures, Yuuhi and Yuamu find a strange spot in the forest where many trees have fallen, forming a scenery similar to a crop circle. As they venture further, they discover a mysterious spaceship and enter it out of curiosity. To their surprise, they come across Yudias Velgear, an alien from the Velgear Star Cluster. As it turns out, Yudias is seeking to learn about Rush Duel—a card game popular among elementary school students—as he believes that it will save his home from a long war. With the siblings agreeing to teach Yudias about Rush Duel, they eventually realize that their first contact with an alien may not be a random coincidence. [Written by MAL Rewrite]

E-Rantel, the capital city of the newly established Sorcerer Kingdom, suffers from a dire shortage of goods. Once a prosperous city known for its trade, it now faces a crisis due to its caution—or even fear—of its king, Ainz Ooal Gown. To make amends, Ainz sends Albedo to the city as a diplomatic envoy. Meanwhile, the cardinals of the Slane Theocracy discuss how to retaliate against Ainz after his attack crippled the Re-Estize Kingdom's army, plotting for the Baharuth Empire to take over the Sorcerer Kingdom. However, when Emperor Jircniv Rune Farlord El Nix arranges a meeting with the Theocracy's messengers at a colosseum, he is confronted by none other than Ainz himself. With their secret gathering now out in the open, the emperor and his guests learn that Ainz has challenged the Warrior King, the empire's greatest fighter, to a duel. With Ainz's motivations beyond his comprehension, Jircniv can do nothing but watch as humanity's future changes before his very eyes. [Written by MAL Rewrite]